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Ultrapyrolysis of automobile shredder residue

机译:汽车碎渣机的超高温分解

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摘要

A fast pyrolysis (Ultrapyrolysis) process was employed to convert automobile shredder residue (ASR) into chemical products. Experiments were conducted at atmospheric pressure and temperatures between 700 and 850\ub0C with residence times between 0.3 and 1.4 seconds. Pyrolysis products included 59 to 68 mass% solid residue, 13 to 23 mass% pyrolysis gas (dry) and 4 to 12 mass% pyrolytic water from a feed containing 39 mass% organic matter and 2 mass% moisture. No measurable amounts of liquid pyrolysis oil were produced. The five most abundant pyrolysis gases, in vol%, were CO (18-29), CO\u2082 (20-23), CH\u2084 (17-22), C\u2082H\u2084 (20-22) and C\u2082H\u2086 (1-ll), accounting for more than 90% of the total volume. The use of a higher organic content ASR feed (58 mass%) resulted in less solid residue and more pyrolysis gas. However, no significant changes were noted in the composition of the pyrolysis gas.
机译:采用快速热解(Ultrapyrolysis)工艺将汽车残渣(ASR)转化为化学产品。实验是在大气压力和700至850℃之间的温度下进行的,停留时间在0.3至1.4秒之间。热解产物包括来自含有39质量%的有机物和2质量%的水分的进料的59至68质量%的固体残余物,13至23质量%的热解气体(干燥)和4至12质量%的热解水。没有产生可测量量的液体热解油。五个最丰富的热解气体,以体积%计为CO(18-29),CO \ u2082(20-23),CH \ u2084(17-22),C \ u2082H \ u2084(20-22)和C \ u2082H \ u2086(1-ll),占总量的90%以上。使用较高有机含量的ASR进料(58质量%)可减少固体残留物并增加热解气体。但是,热解气体的组成没有明显变化。

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